Symposium CB
Progress in Non Conventional and Novel Manufacturing Routes to Ceramics

Programme Chair:
Ralf RIEDEL, Technical University Darmstadt, Germany

Members:
James ADAIR, Penn State University, USA
Dinesh AGRAWAL, Penn State University, USA
Florence BABONNEAU, Université Pierre et Marie Curie, France
Byeong-Soo BAE, KAIST, Korea
Alessandra BIANCO, University of Rome "Tor Vergata", Italy
Joachim BILL, University of Stuttgart, Germany
Ricardo H.R. CASTRO, University of California, Davis, USA
Nachum FRAGE, Ben-Gurion University of the Negev, Israel
Javier GARAY, University of California, Riverside, USA
Peter GREIL, University of Erlangen-Nuernberg, Germany
Young Hwan HAN, Yeungnam University, Korea
Dong Pyo KIM, POSTECH, Korea
Hans-Joachim KLEEBE, Technical University Darmstadt, Germany
Sanjay KUMAR, CSIR-National Metallurgical Laboratory, India
Jennifer LEWIS, University of Illinois at Urbana-Champaign, USA
Yali LI, Tianjin University, China
Jacques LIVAGE, College de France, France
Sylvain MARINEL, ENSICAEN, France
Martha MECARTNEY, University of California, Irvine, USA
Philippe MIELE, Université Montpellier 2, France
Eugene A. OLEVSKY, San Diego State University, USA
Kurosch REZWAN, University of Bremen, Germany
Richard E. RIMAN, Rutgers University, USA
Clement SANCHEZ, Université Pierre et Marie Curie, France
Kenneth SANDHAGE, Georgia Institute of Technology, USA
Saburo SANO, AIST, Japan
Tsugio SATO, Tohoku University, Japan
Julie M. SCHOENUNG, University of California, Davis, USA
Toshimori SEKINE, Hiroshima University, Japan
James SHEN, University of Stockholm, Sweden
Wolfgang SIGMUND, University of Florida, Gainesville, USA
Yoko SUYAMA, Shimane University, Japan
Paula Maria VILARINHO, University of Aveiro, Portugal
Di ZHANG, Shanghai JiaoTong University, China
Igor ZHITOMIRSKY, McMaster University, Canada
Jennifer ANDREW, University of Florida, USA
Frédéric BERNARD, Université de Bourgogne, France
Samuel BERNARD, Universite Montpellier 2, France
Joachim BILL, University of Stuttgart, Germany
Andrzej DEPTULA, Institute of Nuclear Chemistry and Technology, Poland
Claude ESTOURNES, Institut Carnot CIRIMAT, France
Ryoichi FURUSHIMA, AIST, Japan
Rainer GADOW, University of Stuttgart, Germany
Emanuel IONESCU, TU Darmstadt, Germany
Tsutomu MASHIMO, Kumamoto University, Japan
Nadine NASSIF, UPMC, France
Kurosch REZWAN, University of Bremen, Germany
François RIBOT, UPMC, France
Ralf RIEDEL, Technical University Darmstadt, Germany
Tomokazu SANO, Osaka University, Japan
Joerg SCHNEIDER, TU Darmstadt, Germany
Gian Domenico SORARU, University of Trento, Italy
Laura TRECCANI, University of Bremen, Germany
Noboru YOSHIKAWA, Tohoku University, Japan
Di ZHANG, Shanghai JiaoTong University, China
Wang ZHANG, Shanghai Jiao Tong University, China
This symposium will cover recent progress and emerging novel approaches in a selected number of non conventional or novel processing techniques capable of embodying ceramic material with unique properties not achievable or difficult to be achieved with conventional methods and/or provide simplified and/or environmentally benign and energy saving “green” processing routes. Covered will be dense or porous materials, functional nanoparticles*, fibers, thin and thick films, and laminated, composite, graded and hybrid structures that are capable to offer a variety of innovative functions enabling improved electronic, dielectric, magnetic, optical, electrochemical, biomedical and structural applications. Mechanisms and kinetics of processes, new directions and challenges for the design at atomic/molecular scale of complex high performing, micro-, meso- and macro-structures with optimized properties will be enlightened as well as advances on the state-of-the-art computation applied to the design of materials and processing, novel characterization and imaging tools and ongoing and forecast applications.

*Contributions dealing with the synthesis of nanopowders for sintering purposes by the classical ceramic route may be more appropriately submitted to Symposium CA - Ceramic Powders: Advances in Synthesis, Processing and Manufacturing
Session Topics

CB-1 Solution-based processing

Solution-based processing is an attractive and rapidly growing area in the field of materials due to the possibility of reducing the costs of producing various high-quality functional nanoparticles, thin films, fibres, bulk and porous and finely structured materials and devices using relatively low temperatures. A very effective control of stoichiometry, microstructure and morphology and an extreme flexibility in terms of materials and end-use architectures are among the several advantages of this technique.
This Session will report on recent progress in the synthesis of solution processed ceramic materials and related composites and hybrids by techniques such as sol-gel, hydrothermal and solvothermal processing, co-precipitation, spin-coating, spray pyrolysis, electrolytic deposition, etc., and on exploiting their functional properties in view of the diverse applications.

Suggested session topics:
  • Science and technology of solution-based processing of:
    functional nanoparticles
    fibres
    thin film devices, coatings, membranes
    bulk porous and mesoporous materials
    aerogels
    nanocomposite and hybrid structures
  • Functional characterisation and application:
    mechanical
    electronic, dielectric, magnetic, optical
    chemical, electrochemical
    biomedical

CB-2 Polymer derived ceramics

Recent progress in the understanding of the structure at the nanoscale and in the thermodynamics of the complex organic-inorganic systems from which polymer-derived ceramics take origin, coupled with the availability of refined and novel fabrication techniques, enable a more precise control of the strcture of the resulting materials and their embodying with novel powerful functionalities capable to be exploited in a broad range of applications from e.g. energy and environment to aerospace and health-care.
This session will address recent developments in PDCs such as: advanced polymer-to-ceramics conversion methods, structure control and characterisation, thermodynamic aspects and modelling, novel fabrication processes and PDCs device components.

Suggested session topics:
  • Design and synthesis of novel preceramic polymers
  • Conversion mechanisms to oxide and non-oxide ceramics
  • Innovation in fabrication methods for monoliths, fibers, composites, hybrid materials, coatings, membranes, foams
  • Microstructure characterisation
  • Structural and functional properties
  • Thermodynamics and modelling of materials, processes and functions
  • PDCs devices and components for application

CB-3 Microwave processing

In microwave processing the combination of specific features such as volumetric heating, ultra-rapid heating, temperature/time profiles not readily available in conventional processing as well as non thermal microwave effects that enhance mass transport, may result in faster reaction kinetics and densification rates, decreased sintering temperatures, finer and better controlled microstructures, improved physical and mechanical properties. The technique, particularly suited for materials difficult to handle with conventional tools, is being applied to an increasing number of processes and materials paralleling the progress gained in a more fundamental and quantitative understanding of the mechanisms of microwave-materials interactions, in the efficient control of the process and in the advances in production techniques.

Suggested session topics:
  • Advances in the understanding of microwave-materials interaction
  • Dielectric properties measurement
  • Temperature control during microwave processing, non contact temperature sensing systems
  • Microwave assisted synthesis, deposition processes, melting, joining, surface sealing
  • Microwave sintering of oxide and non-oxide ceramics, and composites
  • New theories, and modelling of materials and processes
  • Structural and functional characterisation of materials
  • Advances in production techniques (hybrid heating, sintering in inert atmosphere..)
  • Scale-up of microwave processing and application

CB-4 Spark Plasma and Flash Sintering

Spark Plasma Sintering is a comparatively new technique consisting of directly applied pulsed dc currents and uniaxial pressure to a powdered material in a die with heating rates typically from 100 °C/min up to 1,500 °C/min. The process results in fully dense, fine grained bodies in very short holding time and at considerably lower temperatures (hundreds Celsius degrees) compared to the more conventional sintering and hot pressing techniques.

Owing to its peculiar features, SPS is gaining increased interest for the production of functional nanoceramics from high purity powders, of composites, cermets, coatings, joints and, being SPS a non-equilibrium process, also of materials containing non-equilibrium phases or materials combining different phases that would not normally coexist.

Experimental and theoretical contributions are welcome directed to more precisely define the mechanisms underlying SPS and their effective control, to fix optimum experimental design and to deeply understand and predict the performance of a given material system, both during its consolidation and in final use.

In Flash Sintering, a technique very recently refreshed from metals to the field of ceramics, a direct current field applied by a pair of electrodes to a green ceramic specimen results in a nearly instantaneous (few seconds) densification when the field and the temperature exceed threshold values. This has often been observed to be accompanied by a sharp increase in the electrical conductivity. Exceptional high dnsification rates and low densification temperatures may be obtained with significant time and energy saving, that can be further reduced by application of stress.

The underlying fundamental mechanisms of charge transport, chemical diffusion and the pulse nature of Joule heating effective on the transient phenomena active in flash sintering, and how powder grain size and stoichiometry affect the process appear until now scarcely debated and poorly understood

Contributions are solicited directed to precisely defining the process control parameters to fully exploit the potential of Flash Sintering of ceramics through a deeper insight of the densification mechanisms, and to identify the range of materials, shapes and functions to which the techniques may successfully be applied.

CB-5 Bio-inspired Processing

Comples multifunctional nano structured materials with peculiar and specially designed electrical, magnetic, electro chemical, bioresponsive and structural properties resulting from bio inspired processing routes are stimulating growing research as they involve such diverse areas as molecular recognition and self assembly, self healing, hierarchical patterning, biotemplating and microorganisms-mediated materials synthesis.
Covered by this Session will be topics ranging from the biomolecular- directed growth and microstructure pattern formation of ceramic meso/nanostructures in bulk and thick/thin film, organic-ceramic composites and hybrids, ceramic-metal heterostructures to their embodying with special functionalities for a number of potential applications in, e.g ., high performance light-weight structures, efficient biosensing materials and catalysts, improved biomedical materials with stimuli-adaptive, self-assembly and self-repairing properties and in electronic, optical and photonic devices.

Suggested session topics:
  • Biomineralization
  • Self-assembly
  • Bioclastic processing
  • Sol-gel
  • Soft lithography
  • Layer-by-layer deposition
  • Biomolecule/material interactions
  • Smart bioresponsive materials
  • Materials and process modelling and simulation
  • Bio-inspired materials design vs applications

CB-6 Solid Freeform Fabrication

Solid Freeform Fabrication (SFF) or Rapid Prototyping (RP) includes a very different range of fabrication techniques in which a solid physical model of the part is made directly from a 3-D Computer-Aided Design (CAD) file so offering a new freedom to shape complex parts without the constraints imposed by forming, machining, or joining. Depending on the specific SFF technique, (multi)layered ceramics, membrane-like ceramic structures, complex shaped bulk ceramics may be fabricated by versatile and cost effective means.

Contributions exploiting advances in SFF techniques and applications are sought on the following subjects:
  • Selective Laser Sintering
  • Laminated Object Manufacturing (LOM)
  • Fused Deposition Modelling
  • Stereo lithography
  • 3D-printing
  • Ink-jet printing
  • Extrusion Free Forming

CB-7 Other non traditional or novel routes

  • Ultra-high Pressure Materials Synthesis and Processing
  • Microgravitational Proceesing
  • Directional Solidification from Eutectics
  • Controlled crystallization of Undercooled Glasses
  • Direct Consolidation
  • Others

Special Session CB-9
SHS Ceramics

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Cimtec 2014

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